| Autor: | O. A. Reutov, I. P. Beletskaya, K. P. Butin |
|---|---|
| EAN: | 9781483163833 |
| eBook Format: | |
| Sprache: | Englisch |
| Produktart: | eBook |
| Veröffentlichungsdatum: | 27.10.2016 |
| Untertitel: | A Guide to All Existing Problems of CH-Acidity with New Experimental Methods and Data, Including Indirect Electrochemical, Kinetic and Thermodynamic Studies |
| Kategorie: | |
| Schlagworte: | acidity chemical solutions metal organic organic compound solvent |
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Ch-Acids deals with the acidity of all organic compounds containing C-H bonds. CH-acidity characterizes thermodynamic stability of carbanions in a medium containing a proton donor as carbanion acceptor. The book primarily explains proton transfer stereochemistry or structure in relation to CH-acidity patterns. Methods to study equilibrium acidity; tabulation of pKa values of CH-acids; and equilibrium acidity as a function of CH-acid structures are presented. Topics on kinetic CH-acidity; stereochemistry of proton transfer in CH-acids; and factors obscuring experimental observation of the action of the Bronsted equation are discussed extensively. The text will be of importance to organometallic and organic chemists.