Hydroboration and Organic Synthesis
Autor: | Dhillon, Ranjit S. |
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EAN: | 9783540490753 |
Sachgruppe: | Chemie |
Sprache: | Englisch |
Seitenzahl: | 604 |
Produktart: | Gebunden |
Veröffentlichungsdatum: | 18.05.2007 |
Untertitel: | 9-Borabicyclo [3.3.1] nonane (9-BBN) |
Schlagworte: | Chemie (organisch) Organische Chemie Synthese |
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9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce dienes, enynes, allenes etc. with defined stereochemistry. 9-BBN¿s derivatives have been elegantly used for the asymmetric reduction of ketone moiety. Diels-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations.